Corpus ID: 93411461

Comparing the Stability of Geometrically rigid Tricyclopropyl Carbinyl Cations by $^{19}$F NMR Spectroscopy

@article{Shin1987ComparingTS,
  title={Comparing the Stability of Geometrically rigid Tricyclopropyl Carbinyl Cations by \$^\{19\}\$F NMR Spectroscopy},
  author={Jung‐Hyu Shin and K. Kim and Hunwoo Shin},
  journal={Bulletin of The Korean Chemical Society},
  year={1987},
  volume={8},
  pages={144-145}
}
The relative stability as function of geometry in the rigid tricyclopropylcarbinyl cations with varied bond angle () between the plane of cyclopropane ring and the bond connecting cyclopropane ring to cationic carbon was examined by nmr spectroscopy. 7-p-Fluorophenyltricyclo[2.2.2.]octan-7-yl(4) and 8-p-fluorophenyltricyclo[3.2.2.]nonan-8-yl cation (8) were generated from corresponding tertiary alcohols under stable ion conditions, and their chemical shifts were compared with those of model… Expand