Comparative Study of REDOR and CPPI Derived Order Parameters by 1H-Detected MAS NMR and MD Simulations.

@article{Asami2017ComparativeSO,
  title={Comparative Study of REDOR and CPPI Derived Order Parameters by 1H-Detected MAS NMR and MD Simulations.},
  author={Sam Asami and Bernd Reif},
  journal={The journal of physical chemistry. B},
  year={2017},
  volume={121 37},
  pages={
          8719-8730
        }
}
The measurement of dipolar couplings among directly bonded nuclei yields direct information on the amplitude of dynamic processes in the solid-state. For a reliable motional analysis using, e.g., the model-free approach, a correct quantification of the absolute values of these order parameters is absolutely essential. In the absence of a reference value for the rigid limit, too low dipolar coupling values might be misinterpreted as motion. Therefore, a detailed understanding of the effects that… CONTINUE READING
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