Communication: Observation of local-bender eigenstates in acetylene.


We report the observation of eigenstates that embody large-amplitude, local-bending vibrational motion in acetylene by stimulated emission pumping spectroscopy via vibrational levels of the S1 state involving excitation in the non-totally symmetric bending modes. The N(b) = 14 level, lying at 8971.69 cm(-1) (J = 0), is assigned on the basis of degeneracy… (More)
DOI: 10.1063/1.4928638


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@article{Steeves2015CommunicationOO, title={Communication: Observation of local-bender eigenstates in acetylene.}, author={Adam H Steeves and G Barratt Park and Hans A. Bechtel and Joshua H Baraban and Robert W Field}, journal={The Journal of chemical physics}, year={2015}, volume={143 7}, pages={071101} }