Combined kinetic analysis of solid-state reactions: a powerful tool for the simultaneous determination of kinetic parameters and the kinetic model without previous assumptions on the reaction mechanism.

@article{PrezMaqueda2006CombinedKA,
  title={Combined kinetic analysis of solid-state reactions: a powerful tool for the simultaneous determination of kinetic parameters and the kinetic model without previous assumptions on the reaction mechanism.},
  author={Lu{\'i}s A. P{\'e}rez-Maqueda and Jos{\'e} Manuel Criado and Pedro E. S{\'a}nchez-Jim{\'e}nez},
  journal={The journal of physical chemistry. A},
  year={2006},
  volume={110 45},
  pages={12456-62}
}
The combined kinetic analysis implies a simultaneous analysis of experimental data representative of the forward solid-state reaction obtained under any experimental conditions. The analysis is based on the fact that when a solid-state reaction is described by a single activation energy, preexponetial factor and kinetic model, every experimental T-alpha-dalpha/dt triplet should fit the general differential equation independently of the experimental conditions used for recording such a triplet… CONTINUE READING