Combination of lacunary polyoxometalates and high-nuclear transition metal clusters under hydrothermal conditions: IX. a series of novel polyoxotungstates sandwiched by octa-copper clusters.

@article{Zhao2008CombinationOL,
  title={Combination of lacunary polyoxometalates and high-nuclear transition metal clusters under hydrothermal conditions: IX. a series of novel polyoxotungstates sandwiched by octa-copper clusters.},
  author={Jun-Wei Zhao and Chun-mei Wang and Jie Zhang and Shou-Tian Zheng and Guo-Yu Yang},
  journal={Chemistry},
  year={2008},
  volume={14 30},
  pages={
          9223-39
        }
}
The reaction of CuCl(2).2 H2O with trivacant Keggin polyoxoanions K8Na2[A-alpha-GeW9O34].25 H2O or K10[A-alpha-SiW9O34].25 H2O in the presence of 1,2-diaminopropane (dap), ethylenediamine (en) or 2,2'-bipyridine (2,2'-bpy) under hydrothermal conditions afforded five novel hybrid inorganic-organic octa-Cu sandwiched polyoxotungstates (POTs): H4[CuII8(dap)4(H2O)2(B-alpha-GeW9O34)2].13 H2O (1), (H2en)2[CuII8-(en)4(H2O)2(B-alpha-GeW9O34)2].5 H2O(2), (H2en)2[CuII8(en)4(H2O)2(B-alpha-SiW9-O34)2].8… CONTINUE READING

References

Publications referenced by this paper.
SHOWING 1-8 OF 8 REFERENCES

SHELXS97, Program for Crystal Structure Solution

G. M. Sheldrick
  • Gçttingen: Gçttingen, Germany,
  • 1997
VIEW 1 EXCERPT

Domaille, Inorganic Syntheses

a N. Haraguchi, Y. Okaue, T. Isobe, Y. Matsuda, Inorg. Chem
  • Inorg. Chem. 2006,
  • 1994

Molecular Magnetism, VCH

O. Kahn
  • New York,
  • 1993
VIEW 1 EXCERPT

2253, and references therein

G. Nord, A. C. Hazell, R. G. Hazell, O. Farver, Inorg. Chem
  • Inorg. Chim. Acta,
  • 1983

Crystallogr

O. V. Dolomanov, A. J. Blake, N. R. Champness, M. Schrçder, J. Appl
  • 2003, 36,
  • 1283
VIEW 2 EXCERPTS

Phys

B. E. Myers, L. Berger, S. A. Friedberg, J. Appl
  • 1968, 40,
  • 1149
VIEW 1 EXCERPT

Inorganic Syntheses , John Wiley and Sons , New York , 1990 , 27 , 108 ; i ) R . Contant , A . TQzQ

A. TQzQ G. HervQ, R. G. Finke, M. W. Droege, P. J. Domaille
  • Inorganic Syntheses