Color-Tunable and White-Light Luminescence in Lanthanide-Dicyanoaurate Coordination Polymers.

  title={Color-Tunable and White-Light Luminescence in Lanthanide-Dicyanoaurate Coordination Polymers.},
  author={Ryan J Roberts and Debbie Le and Daniel B. Leznoff},
  journal={Inorganic chemistry},
  volume={56 14},
The new lanthanide-dicyanoaurate coordination polymers [nBu4N]2[Ln(NO3)4Au(CN)2] (Ln = Sm, Dy) and Sm[Au(CN)2]3·3H2O were prepared and structurally characterized and their luminescence spectra described. The emissions of solid-solutions of [nBu4N]2[Ln(NO3)4Au(CN)2] (Ln = Ce, Sm, Eu, Tb, and Dy) were explored with an emphasis on their capacity for luminescent color tuning and white-light emission via the selection of composition, excitation wavelength, and temperature. Specifically, the binary… CONTINUE READING
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