Collisional cooling of large ions in electrospray mass spectrometry.

@article{Chernushevich2004CollisionalCO,
  title={Collisional cooling of large ions in electrospray mass spectrometry.},
  author={Igor V Chernushevich and Bruce A. Thomson},
  journal={Analytical chemistry},
  year={2004},
  volume={76 6},
  pages={
          1754-60
        }
}
Collisional cooling of ions in the rf-only multipole guides has become a method of choice for coupling electrospray sources to various mass analyzers. Normally parameters of such ion guides (length, pressure) provide enough thermalization and focusing for ions in a wide mass range. Noncovalent complexes, however, have more compact conformations than denatured biomolecules of similar mass and, therefore may not be transmitted efficiently through standard ion guides, as demonstrated by… CONTINUE READING

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