Citrinadin A, a novel pentacyclic alkaloid from marine-derived fungus Penicillium citrinum.

@article{Tsuda2004CitrinadinAA,
  title={Citrinadin A, a novel pentacyclic alkaloid from marine-derived fungus Penicillium citrinum.},
  author={M. Tsuda and Yuu Kasai and K. Komatsu and T. Sone and Michiko Tanaka and Y. Mikami and J. Kobayashi},
  journal={Organic letters},
  year={2004},
  volume={6 18},
  pages={
          3087-9
        }
}
[structure: see text] A novel pentacyclic alkaloid, citrinadin A (1), was isolated from the cultured broth of the fungus Penicillium citrinum, which was separated from a marine red alga, and the structure was elucidated by spectroscopic data. The relative stereochemistry of the pentacyclic core was assigned on the basis of NOESY data and (1)H-(1)H coupling constants, and the presence of an N,N-dimethyl-L-valine residue in 1 was determined by chiral HPLC analysis of the hydrolysate. 
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