Circularly polarized luminescence in enantiopure europium and terbium complexes with modular, all-oxygen donor ligands.

@article{Seitz2009CircularlyPL,
  title={Circularly polarized luminescence in enantiopure europium and terbium complexes with modular, all-oxygen donor ligands.},
  author={Michael Seitz and King Do and Andrew J. Ingram and Evan G. Moore and Gilles Muller and Kenneth N Raymond},
  journal={Inorganic chemistry},
  year={2009},
  volume={48 17},
  pages={8469-79}
}
The modular syntheses of three new octadentate, enantiopure ligands are reported, one with the bidentate chelating unit 2-hydroxyisophthalamide (IAM) and two with bidentate 1-hydroxy-2-pyridinone (1,2-HOPO) units. A new design principle is introduced for the chiral, non-racemic hexamines which constitute the central backbones for the presented class of… CONTINUE READING