Chiral recognition in diaziridine clusters and the problem of racemization waves.

@article{Alkorta2007ChiralRI,
  title={Chiral recognition in diaziridine clusters and the problem of racemization waves.},
  author={Ibon Alkorta and Jos{\'e} Elguero and Krzysztof Zborowski},
  journal={The journal of physical chemistry. A},
  year={2007},
  volume={111 6},
  pages={1096-103}
}
Theoretical calculations (B3LYP/6-31+G**) of chiral clusters of diaziridines have been carried out. Five configurations of chiral and nonchiral clusters with up to eight monomers have been considered. The proton transfer within the neutral and protonated clusters has been studied as a possible source of racemization waves. The optical rotatory power (ORP… CONTINUE READING