Chiral magnetic metal-organic frameworks of Mn(II) with achiral tetrazolate-based ligands by spontaneous resolution.


The enantiomers of complex 1 (1a and 1b) have been obtained by spontaneous resolution upon crystallization in the absence of a chiral source. The enantiomeric nature of 1a and 1b was confirmed by circular dichroism (CD) spectra and theoretical investigation. 
DOI: 10.1039/c0cc03111a

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