Chiral [Mo8O26]4- Polyoxoanion-Induced Three-Dimensional Architectures With Homochiral Eight-Fold Interpenetrated Metal-Organic Frameworks.

Abstract

A pair of novel chiral compounds based on homochiral 8-fold interpenetrated metal-organic frameworks (MOFs) and chiral polyoxometalates (POMs), formulated as d-[Cu(4,4'-bipy)1.5]4[Mo8O26] (d-1) and l-[Cu(4,4'-bipy)1.5]4[Mo8O26] (l-1) (4,4'-bipy = 4,4'-bipyridine), have been successfully synthesized and characterized by single crystal X-ray diffraction… (More)
DOI: 10.1021/acs.inorgchem.7b01057

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