Chemoselective Alkene Hydrosilylation Catalyzed by Nickel Pincer Complexes.

Abstract

Chemoselective hydrosilylation of functionalized alkenes is difficult to achieve using base-metal catalysts. Reported herein is that well-defined bis(amino)amide nickel pincer complexes are efficient catalysts for anti-Markovnikov hydrosilylation of terminal alkenes with turnover frequencies of up to 83,000 per hour and turnover numbers of up to 10,000… (More)
DOI: 10.1002/anie.201507829

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@article{Buslov2015ChemoselectiveAH, title={Chemoselective Alkene Hydrosilylation Catalyzed by Nickel Pincer Complexes.}, author={Ivan Buslov and Jeanne Becouse and Simona Mazza and Mickael Montandon-Clerc and Xile Hu}, journal={Angewandte Chemie}, year={2015}, volume={54 48}, pages={14523-6} }