Chemie polyfunktioneller Liganden, 53 [1] Über methyl-substituierte Triarsa-trioxa-, Triarsa-trithiaund Triarsa-triaza-adamantane und über den stark aufgeweiteten Adamantan-Käfig im Schwefel-Derivat / Chemistry of Polyfunctional Ligands, 53 [1] About Methyl-substituted Triarsa-trioxa-, Triarsa-trith

@article{Ellermann1979ChemiePL,
  title={Chemie polyfunktioneller Liganden, 53 [1] {\"U}ber methyl-substituierte Triarsa-trioxa-, Triarsa-trithiaund Triarsa-triaza-adamantane und {\"u}ber den stark aufgeweiteten Adamantan-K{\"a}fig im Schwefel-Derivat / Chemistry of Polyfunctional Ligands, 53 [1] About Methyl-substituted Triarsa-trioxa-, Triarsa-trith},
  author={Jochen Ellermann and Martin Lietz and Peter Merbach and Gerhard Thiele and Gerd Zoubek},
  journal={Zeitschrift f{\"u}r Naturforschung B},
  year={1979},
  volume={34},
  pages={975 - 982}
}
Abstract The reaction of l,l,l-tris(diiodarsinomethyl)ethane, CH3C(CH2Asl2)3 (1), with H2O, H2S and CH3NH2 in THF gives the adamantane cage compounds CH3C(CH2ASO)3 (4), CH3C(CH2ASS)3 (5) and CH3C(CH2ASNCH3)3 (6) in high yields. The crystal structure of 5 has been determinated by X-ray diffraction. The unit cell (space group P2i/w) contains 4 isolated molecules in a cubic closest packing. The heteroadamantane 5 has an enlarged cage structure with extremely spread C-C(H2)-As bond angles of 124… Expand
12 Citations
Chemie Polyfunktioneller Molekülle: XCIX. Hydrolyse und oxidative Hydrolyse von Tetrakis[(diiodarsino) methyl]methan. Kristallstrukturanalyse eines Organoarsenoxid-Arsonigsäure-Derivats
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Chemie polyfunktioneller liganden : LXVIII. Chrom-, molybdän- und wolframcarbonyl-komplexe des 7-methyl-1,3,5-triarsa-2,4,9-trioxa-adamantans
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Chemie polyfunktioneller Moleküle, 78. Noradamantane mit den Heteroelementen Arsen, Sauerstoff, Schwefel und Selen
Durch Reduktion des Hetero-adamantans CH3C(CH2AsO)3 (1a) mit alkalischer Hypophosphitlosung erhalt man das Hetero-noradamantan CH3C(CH2As)3O2 (2a) neben CH3C(CH2As)3 (3). Die homologen NoradamantaneExpand
Chemie polyfunktioneller Moleküle, 88. (Chlormethyl)tris[(diiodarsino)methyl]methan und seine Verwendung zur Synthese offenkettiger, bi- und tricyclischer Organo-Arsen-Verbindungen
Tetrakis(chlormethyl)methan, C(CH2Cl)4 reagiert mit NaAs(C6H5)2(Molverhaltnis 1:4) in flussigem Ammoniak lediglich zum tritertiaren Arsan ClCH2C[CH2As(C6H5)2]3 (1). Dieses setzt sich mit gasformigemExpand
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The resolution and improved synthesis of the naturally occurring, adamantane-type, tetraarsenical (±)-Arsenicin A is reported. The five-step synthesis of (±)-Arsenicin A fromExpand
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