Chemically triggered C-ON bond homolysis in alkoxyamines. 6. Effect of the counteranion.

Abstract

We showed (J. Org. Chem. 2012, 77, 9634) that the activation by methylation of pyridyl-based alkoxyamine 1 increased with the hydrogen bond donor properties of solvents. In this paper, activation of 1 by protonation with acids, CF3COOH and CSA, in tert-butylbenzene (t-BuPh) and in H2O/MeOH afforded, with CF3COOH, k(d) 28-fold larger in H2O/MeOH than in t… (More)
DOI: 10.1021/jo401227a

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@article{Audran2013ChemicallyTC, title={Chemically triggered C-ON bond homolysis in alkoxyamines. 6. Effect of the counteranion.}, author={G{\'e}rard Audran and Paul Br{\'e}mond and Sylvain R A Marque and Germain Obame}, journal={The Journal of organic chemistry}, year={2013}, volume={78 15}, pages={7754-7} }