Characterization of key intermediates in a complex organocatalytic cascade reaction using mass spectrometry.

@article{Schrader2009CharacterizationOK,
  title={Characterization of key intermediates in a complex organocatalytic cascade reaction using mass spectrometry.},
  author={Wolfgang Schrader and Peni Purwa Handayani and Jian Zhou and Benjamin List},
  journal={Angewandte Chemie},
  year={2009},
  volume={48 8},
  pages={
          1463-6
        }
}
Chemical scrabble: Mechanistic studies of complex organocatalytic cascade reactions are challenging owing to the presence of many species involved. Electrospray ionization mass spectrometry provides details about a one-pot quadruple organocatalytic cascade reaction, and allows detailed characterization of the reaction and its key intermediates. 
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High resolution mass data of detected intermediates. Species Mass (measured) Mass (theoretical) Formula Error

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