Characteristics of fast mediated bioelectrocatalytic reaction near microelectrodes.

@article{Kitazumi2014CharacteristicsOF,
  title={Characteristics of fast mediated bioelectrocatalytic reaction near microelectrodes.},
  author={Yuki Kitazumi and Tatsuo Noda and Osamu Shirai and Masahiro Yamamoto and Kenji Kano},
  journal={Physical chemistry chemical physics : PCCP},
  year={2014},
  volume={16 19},
  pages={
          8905-10
        }
}
The pseudo-steady-state current due to a mediated enzymatic reaction on a microelectrode is characterized on the basis of theoretical analysis and numerical simulation. The steady-state current is proportional to substrate concentration when the enzymatic reaction is considerably faster than substrate mass transport via nonlinear diffusion. Under such conditions, the reaction plane, where the mass flow of the substrate is converted to that of the mediator, exists near the electrode surface. The… 

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