Chapter 3 – SOLVATION OF IONS

@inproceedings{Amis1973Chapter3,
  title={Chapter 3 – SOLVATION OF IONS},
  author={E. Stephen Amis and James F. Hinton},
  year={1973}
}
42 Citations
Apparent Molal Volume and Compressibility of Glucose and Maltose at Different Temperatures in Lysozyme Solution
In the present research, we study the thermodynamic parameters of ternary system of two different sugars, i.e., (a)D(-)glucose+lysozyme+water and (b)maltose+lysozyme+water. It has been done at
Density and Partial Molar Volume of Cetyltrimethylammonium Bromide in the Presence and Absence of KCl and NaCl in Aqueous Media at Room Temperature
The density of cetyltrimethylammonium bromide in pure water and in the presence of KCl and NaCl at room temperature are reported. The concentrations of cetyltrimethylammonium bromide are varied from
High-resolution whole-brain staining for electron microscopic circuit reconstruction
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A preparation, BROPA (brain-wide reduced-osmium staining with pyrogallol-mediated amplification), that results in the preservation and staining of ultrastructural details throughout the brain at a resolution necessary for tracing neuronal processes and identifying synaptic contacts between them is described.
Design and construction of an quasi-adiabatic dissolution calorimeter with a novel dosing apparatus and a low heat capacity
A quasi-adiabatic calorimeter for determining the molar solution enthalpies (ΔsolH) of non-volatile solids was constructed. The design of the instrument was adjusted to allow the determination of
Models of the equilibrium distribution of organic chemicals between water and solid phases of environmental media
Water–solid phase equilibrium distributions are foundational to multimedia environmental fate models of anthropogenic organic chemicals. This contextual review of equilibrium models of ionizing
Philicity and Fugality Scales for Organic Reactions
Theoretical scales of reactivity and selectivity are important tools to explain and to predict reactivity patterns, including reaction mechanisms. The main achievement of these efforts has been the
Physico-Chemical Studies of Vitamin-C in Aqueous 2-Propanol: Manifestation of Molecular Interactions
The apparent molar volume (ϕV), viscosity B-coefficient, and molar refraction (Rm) of l-ascorbic acid have been determined in (40, 60 and 80 mass%) water and 2-propanol solutions at 298.15, 308.15
What Protein Charging (and Supercharging) Reveal about the Mechanism of Electrospray Ionization
TLDR
A single mechanism can be formulated to explain how reagents that promote analyte charging (“supercharging”) such as m-NBA, sulfolane, and 3-nitrobenzonitrile increase analyte charge from “denaturing” and “native” solvent systems.
Nucleophilic Substitution Reactions of 2,4-Dinitrobenzene Derivatives with Hydrazine: Leaving Group and Solvent Effects
The hydrazinolysis of 2,4-dinitrophenyl acetate in methanol proceed exclusively through acyl-oxygen scission by a concerted mechanism. The reaction of 1-chloro-2,4-dinitrobenzene with hydrazine in
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References

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NMR Studies of Aqueous Electrolyte Solutions. IV. Hydration Numbers of Strong Electrolytes Determined from Temperature Effects on Proton Shifts
Total effective hydration numbers for a variety of strong electrolytes are deduced from temperature dependence of proton shifts. Individual hydration of the cations and anions are speculated. The
Solvation Number of the Electron in Liquid Ammonia. A Nitrogen Magnetic Relaxation Study
The high resolution proton magnetic resonance spectrum of a dilute solution of potassium in liquid ammonia shows a large contribution to the line shape from 14N spin–lattice relaxation through
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