Cation-dependent magnetic ordering and room-temperature bistability in azido-bridged perovskite-type compounds.

@article{Zhao2013CationdependentMO,
  title={Cation-dependent magnetic ordering and room-temperature bistability in azido-bridged perovskite-type compounds.},
  author={Xin-hua Zhao and Xing-Cai Huang and Shao-liang Zhang and Dong Shao and Haiyan Wei and Xin-Yi Wang},
  journal={Journal of the American Chemical Society},
  year={2013},
  volume={135 43},
  pages={
          16006-9
        }
}
A series of end-to-end azido-bridged perovskite-type compounds [(CH3)nNH4-n][Mn(N3)3] (n = 1-4) were synthesized and characterized. Structural phase transitions indicating the general lattice flexibility were observed and confirmed by the crystal structures of different phases. These materials show cation-dependent magnetic ordering at up to 92 K and magnetic bistability near room temperature. 
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