Catalytic regioselective oxidation of glycosides.


Discrimination among equals: A catalytic method for the selective oxidation of unprotected glycosides, both monosaccharides and disaccharides, has been developed. The resulting ketosaccharides are isolated in moderate to excellent yields. This approach provides a basis for protecting-group-free synthetic transformations of carbohydrates.

DOI: 10.1002/anie.201301662

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@article{Jger2013CatalyticRO, title={Catalytic regioselective oxidation of glycosides.}, author={Manuel J{\"a}ger and Marcel Hartmann and Johannes G de Vries and Adriaan J Minnaard}, journal={Angewandte Chemie}, year={2013}, volume={52 30}, pages={7809-12} }