Catalytic oxidation of 5-hydroxymethylfurfural into 2,5-diformylfuran using V-containing heteropoly acid catalysts

@article{Rodikova2020CatalyticOO,
  title={Catalytic oxidation of 5-hydroxymethylfurfural into 2,5-diformylfuran using V-containing heteropoly acid catalysts},
  author={Yulia Rodikova and Elena Zhizhina},
  journal={Reaction Kinetics, Mechanisms and Catalysis},
  year={2020},
  volume={130},
  pages={403-415}
}
2,5-Diformylfuran (DFF) is an attractive and challenging compound that can be synthesized with good selectivity by the oxidation of bio-based 5‐hydroxymethylfurfural (5-HMF) using specific catalysts. Vanadium-containing heteropoly acids (PMoV HPAs) are highly active oxidation catalysts whose activity can be tuned by changing vanadium(V) (V V ) content. This study reports the preparation of a number of PMoV HPAs with different V V amount and type of outer-sphere cation and investigating their… 
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References

SHOWING 1-10 OF 33 REFERENCES
Aerobic oxidation of 5-hydroxymethylfurfural to 2,5-diformylfuran on supported vanadium oxide catalysts: Structural effect and reaction mechanism
The structure–activity relationship and reaction mechanism for selective oxidation of 5-hydroxymethylfurfural (HMF) to 2,5-diformylfuran (DFF) in toluene were studied on vanadium oxide domains on
Base-free aerobic oxidation of 5-hydroxymethylfurfural to 2,5-furandicarboxylic acid over a Pt/C–O–Mg catalyst
Base-free aerobic oxidation of 5-hydroxymethylfurfural (HMF) to 2,5-furandicarboxylic acid (FDCA) was realized successfully based on the design of a novel Pt/C–O–Mg catalyst. The properties of this
Optimization of Co/Mn/Br-Catalyzed Oxidation of 5-Hydroxymethylfurfural to Enhance 2,5-Furandicarboxylic Acid Yield and Minimize Substrate Burning
2,5-Furandicarboxylic acid (FDCA) is a valuable nonphthalate biomass-based plastic precursor with the potential to replace terephthalic acid (TPA) in a variety of polymer applications. In this work,
One-pot, one-step synthesis of 2,5-diformylfuran from carbohydrates over Mo-containing Keggin heteropolyacids.
TLDR
This work develops a one-pot strategy for directly converting fructose into 2,5-diformylfuran (DFF) over Mo-containing Keggin heteropolyacids (HPAs) in open air with high activity and selectivity to the formation of DFF owing to its higher Brønsted acidity and moderate redox potential.
Chemicals from Biomass: Aerobic Oxidation of 5-Hydroxymethyl-2-Furaldehyde into Diformylfurane Catalyzed by Immobilized Vanadyl-Pyridine Complexes on Polymeric and Organofunctionalized Mesoporous Supports
Diformylfurane (DFF) has been obtained by aerobic oxidation of 5-hydroxymethyl-2-furaldehyde (HMF) with homogeneous pyridine-vanadyl complexes in homogeneous phase, with Cu and V in
Catalytic Performance of Zeolite‐Supported Vanadia in the Aerobic Oxidation of 5‐hydroxymethylfurfural to 2,5‐diformylfuran
The catalytic performance of zeolite‐supported vanadia catalysts was examined for the aerobic oxidation of 5‐hydroxymethylfurfural (HMF) to 2,5‐diformylfuran (DFF) in organic solvents such as
Regeneration of the Oxidation Catalysts Based on the Aqueous Solutions of Non‐Keggin Mo‐V‐P Heteropoly Acids by Molecular Oxygen
ABSTRACT: Kinetic peculiarities of regeneration of the aqueous solutions of non-Keggin-typeMo-V-P heteropoly acids H a P z Mo y V x O b (HPA-x ) and their acidic salts by O 2 are studied. TheHPA- x
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