Catalytic oxidation of 5-hydroxymethylfurfural into 2,5-diformylfuran using V-containing heteropoly acid catalysts

  title={Catalytic oxidation of 5-hydroxymethylfurfural into 2,5-diformylfuran using V-containing heteropoly acid catalysts},
  author={Yulia Rodikova and Elena Zhizhina},
  journal={Reaction Kinetics, Mechanisms and Catalysis},
2,5-Diformylfuran (DFF) is an attractive and challenging compound that can be synthesized with good selectivity by the oxidation of bio-based 5‐hydroxymethylfurfural (5-HMF) using specific catalysts. Vanadium-containing heteropoly acids (PMoV HPAs) are highly active oxidation catalysts whose activity can be tuned by changing vanadium(V) (V V ) content. This study reports the preparation of a number of PMoV HPAs with different V V amount and type of outer-sphere cation and investigating their… 
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The structure–activity relationship and reaction mechanism for selective oxidation of 5-hydroxymethylfurfural (HMF) to 2,5-diformylfuran (DFF) in toluene were studied on vanadium oxide domains on
Base-free aerobic oxidation of 5-hydroxymethylfurfural to 2,5-furandicarboxylic acid over a Pt/C–O–Mg catalyst
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Regeneration of the Oxidation Catalysts Based on the Aqueous Solutions of Non‐Keggin Mo‐V‐P Heteropoly Acids by Molecular Oxygen
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