Catalytic oxidation of 5-hydroxymethylfurfural into 2,5-diformylfuran using V-containing heteropoly acid catalysts

@article{Rodikova2020CatalyticOO,
  title={Catalytic oxidation of 5-hydroxymethylfurfural into 2,5-diformylfuran using V-containing heteropoly acid catalysts},
  author={Yulia Rodikova and E. Zhizhina},
  journal={Reaction Kinetics, Mechanisms and Catalysis},
  year={2020},
  volume={130},
  pages={403-415}
}
2,5-Diformylfuran (DFF) is an attractive and challenging compound that can be synthesized with good selectivity by the oxidation of bio-based 5‐hydroxymethylfurfural (5-HMF) using specific catalysts. Vanadium-containing heteropoly acids (PMoV HPAs) are highly active oxidation catalysts whose activity can be tuned by changing vanadium(V) (V V ) content. This study reports the preparation of a number of PMoV HPAs with different V V amount and type of outer-sphere cation and investigating their… Expand

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