Catalytic isomerization of quadricyclane using fourier transform near-infrared absorption spectroscopy: diffusion, conversion, and temperature effect.

@article{Fan2006CatalyticIO,
  title={Catalytic isomerization of quadricyclane using fourier transform near-infrared absorption spectroscopy: diffusion, conversion, and temperature effect.},
  author={Hsiu-Fang Fan and Chia-yu Chang and Thou-Long Chin and T. Ho and King-Chuen Lin},
  journal={The journal of physical chemistry. B},
  year={2006},
  volume={110 11},
  pages={5563-9}
}
By using Fourier transform near-infrared (NIR) absorption spectroscopy, the kinetic behaviors of quadricyclane isomerization, as catalyzed by anhydrous CuSO(4) in chloroform mixture with and without agitation, are presented. Given the acquired NIR spectra, the concentration decay of quadricyclane with the reaction time is determined with the aid of partial least-squares analysis. When the mixture is not agitated, the diffusion coefficients in chloroform are evaluated to be (3.8 +/- 0.1) x 10(-5… CONTINUE READING

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