Catalytic hydrogenolysis of aromatic ketones in mixed choline-betainium ionic liquids.

Abstract

The palladium-catalyzed hydrogenolysis of aromatic ketones to alkylbenzenes was studied in mixtures of ionic liquids to explore the promotional effect of these reaction media. Choline-based ionic liquids displayed complete miscibility with the aromatic ketone substrate at reaction temperature and a clear phase separation of the derived alkylbenzene product… (More)
DOI: 10.1002/cssc.200800140

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