Catalytic hydrogenation of carbon dioxide using Ir(III)-pincer complexes.

@article{Tanaka2009CatalyticHO,
  title={Catalytic hydrogenation of carbon dioxide using Ir(III)-pincer complexes.},
  author={Ryo Tanaka and Makoto Yamashita and Kyoko Nozaki},
  journal={Journal of the American Chemical Society},
  year={2009},
  volume={131 40},
  pages={14168-9}
}
Catalytic hydrogenation of carbon dioxide in aqueous potassium hydroxide was performed using a newly synthesized isopropyl-substituted PNP-pincer iridium trihydride complex as a catalyst. Potassium formate was obtained with turnover numbers up to 3,500,000 and a turnover frequency of 150,000 h(-1), both of which are the highest values reported to date. 

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Formic Acid

  • W. Reutemann, H. Kieczka
  • Ullmann ’ s Encyclopedia of Industrial Chemistry…
  • 2009

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