Catalytic hydrogen atom transfer (HAT) for sustainable and diastereoselective radical reduction.

@article{Gansuer2012CatalyticHA,
  title={Catalytic hydrogen atom transfer (HAT) for sustainable and diastereoselective radical reduction.},
  author={Andreas Gans{\"a}uer and Max Klatte and Gerhard Markus Br{\"a}ndle and Joachim Friedrich},
  journal={Angewandte Chemie},
  year={2012},
  volume={51 35},
  pages={8891-4}
}
Radical reduction by HAT (hydrogen atom transfer) is an essential step in numerous radical reactions. While transition-metal hydrides are in principle excellent reagents for this purpose because of their low bond dissociation energies, their use in such reactions is attractive only when they serve as catalysts. The ideal catalyst for such a process should… CONTINUE READING
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