Catalytic enantioselective desymmetrisation as a tool for the synthesis of hodgkinsine and hodgkinsine B.

@article{Snell2012CatalyticED,
  title={Catalytic enantioselective desymmetrisation as a tool for the synthesis of hodgkinsine and hodgkinsine B.},
  author={R. Snell and M. J. Durbin and R. L. Woodward and M. Willis},
  journal={Chemistry},
  year={2012},
  volume={18 52},
  pages={
          16754-64
        }
}
  • R. Snell, M. J. Durbin, +1 author M. Willis
  • Published 2012
  • Chemistry, Medicine
  • Chemistry
  • Two palladium-catalysed amination protocols are deployed in the desymmetrisation of the complex dimeric alkaloid meso-chimonanthine. The power of these transformations is showcased in an efficient formal and total synthesis of the natural products hodgkinsine and hodgkinsine B, respectively. 
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