Catalytic Reduction of Dinitrogen to Ammonia at a Single Molybdenum Center

@article{Yandulov2003CatalyticRO,
  title={Catalytic Reduction of Dinitrogen to Ammonia at a Single Molybdenum Center},
  author={D. Yandulov and R. Schrock},
  journal={Science},
  year={2003},
  volume={301},
  pages={76 - 78}
}
  • D. Yandulov, R. Schrock
  • Published 2003
  • Chemistry, Medicine
  • Science
  • Dinitrogen (N2) was reduced to ammonia at room temperature and 1 atmosphere with molybdenum catalysts that contain tetradentate [HIPTN3N]3– triamidoamine ligands {such as [HIPTN3N]Mo(N2), where [HIPTN3N]3– is [{3,5-(2,4,6-i-Pr3C6H2)2C6H3NCH2CH2}3N]3–} in heptane. Slow addition of the proton source [{2,6-lutidinium}{BAr′4}, where Ar′ is 3,5-(CF3)2C6H3]and reductant (decamethyl chromocene) was critical for achieving high efficiency (∼66% in four turnovers). Numerous x-ray studies, along with… CONTINUE READING
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