Catalysis by Haemin of some Molybdenum (VI) Oxidations

Abstract

WE report a novel series of oxidations by molybdenum (VI) in acid solution, catalysed by trace amounts of biologically important ferric complexes. These systems extend our knowledge of the catalytic action of haem centres in redox processes and, because of the remarkable specificity involved, may help to investigate isopolyanion equilibria. Catalysts… (More)
DOI: 10.1038/219605a0

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