Cascade complexation: a single cyano bridge links a pair of Cu(II) cations.

@article{Bond2005CascadeCA,
  title={Cascade complexation: a single cyano bridge links a pair of Cu(II) cations.},
  author={Andrew D Bond and Sofia Derossi and Charles J. Harding and Eric J. L. McInnes and Vickie McKee and Christine J McKenzie and Jane Nelson and Joanna Wolowska},
  journal={Dalton transactions},
  year={2005},
  volume={14},
  pages={
          2403-9
        }
}
A series of structurally characterised mu-cyanodicopper(II) cryptates shows moderately strong antiferromagnetic interaction in the range -2J= 150-200 cm(-1), at the high end of the observed range for such assemblies. The lowest magnetic exchange coupling parameter is displayed where there is slight bending of the M-CN-M assembly, enforced by the constraints of cryptate encapsulation. Thermally accessible triplet EPR spectra are observed with zero-field splittings of the order of 0.13-0.14 cm(-1… CONTINUE READING

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