Carboranes in the chemist's toolbox.

@article{Grimes2015CarboranesIT,
  title={Carboranes in the chemist's toolbox.},
  author={Russell N. Grimes},
  journal={Dalton transactions},
  year={2015},
  volume={44 13},
  pages={
          5939-56
        }
}
  • R. Grimes
  • Published 17 March 2015
  • Chemistry
  • Dalton transactions
Once seldom encountered outside of a few laboratories, carboranes are now everywhere, playing a role in the development of a broad range of technologies encompassing organic synthesis, radionuclide handling, drug design, heat-resistant polymers, cancer therapy, nanomaterials, catalysis, metal-organic frameworks, molecular machines, batteries, electronic devices, and more. This perspective highlights selected examples in which the special attributes of carboranes and metallacarboranes are being… 
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155 Citations
Background Citations
5

155 Citations

Recent advances in the chemistry of carborynes

Chapter 17 – Carboranes in Other Applications

Controlled functionalization of o-carborane via transition metal catalyzed B-H activation.

A review of recent advances in transition metal catalyzed vertex-specific BH functionalization of carbon-boron molecular clusters concludes that selection of a cage C-H bonds for functionalization is very challenging.

The closo-Dodecaborate Dianion Fused with Oxazoles Provides 3D Diboraheterocycles with Selective Antimicrobial Activity.

3D heterocycles exhibit strong and selective antimicrobial activity against Neisseria gonorrhoeae, a widespread bacterial pathogen that has shown increasing incidences of multidrug resistance and for which the development of new antimicrobial compounds is urgently needed.

Carboranes as Aryl Mimetics in Catalysis: A Highly Active Zwitterionic NHC-Precatalyst.

A straightforward synthetic route to a novel zwitterionic triazolium-based N-heterocyclic carbene (NHC) precatalyst bearing a 7,8-dicarba-nido-undecaboranyl substituent is reported, showing the catalyst's excellent activity and its broad applicability are demonstrated in a wide range of organocatalytic transformations.

Phosphine oxide-directed palladium-catalyzed B(3)–H arylation of o-carboranes

Recent advances in the selective functionalization of anionic icosahedral boranes and carboranes

Tethered N-Heterocyclic Carbene-Carboranyl Silver Complexes for Cancer Therapy

Silver complexes of tethered N-heterocyclic carbene-carboranyl ligands have been prepared and fully characterized. The first example of silver bonded directly to the cage of o-carborane has been…

High-yielding and facile synthesis of organosilicon compounds containing a m-carboranylmethyl group

An efficient method for the synthesis of organosilicon compounds containing m-carboranylmethyl was developed, which afforded the products in good to excellent yields (up to 88%) compared to the…

Recent advances in B–H functionalization of icosahedral carboranes and boranes by transition metal catalysis

Abstract Significant progress in the functionalization of icosahedral boron clusters has been made in the past years, leading to an increasing number of applications in various fields of research.…
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