Carborane complexes of ruthenium(III): studies on thermal reaction chemistry and the catalyst design for atom transfer radical polymerization of methyl methacrylate.

@article{Grishin2011CarboraneCO,
  title={Carborane complexes of ruthenium(III): studies on thermal reaction chemistry and the catalyst design for atom transfer radical polymerization of methyl methacrylate.},
  author={Ivan D Grishin and Dmitrii I D'yachihin and Alexander V Piskunov and Fedor M. Dolgushin and Alexander F Smol'yakov and Mikhail M Il'in and Vadim A Davankov and Igor T. Chizhevsky and Dmitry F Grishin},
  journal={Inorganic chemistry},
  year={2011},
  volume={50 16},
  pages={7574-85}
}
The heating of the 18-electron complex [3,3-(dppb)-3-H-3-Cl-closo-3,1,2-RuC(2)B(9)H(11)] (3) in benzene at 80 °C in the presence of a small amount of CCl(4) as initiator afforded paramagnetic 17-electron species [3,3-(dppb)-3-Cl-closo-3,1,2-RuC(2)B(9)H(11)] (4) along with minor amounts of two P-phenylene ortho-cycloboronated derivatives [3-Cl-3,3,8-{Ph(2)P… CONTINUE READING