Carbon dioxide clathrate hydrates: selective role of intermolecular interactions and action of the SDS catalyst.


The ability of a single sodium dodecyl sulfate (SDS) molecule to promote the formation of CO2 clathrate hydrates in water (as it does for methane) has been investigated at the microscopic level. For this purpose, the components of the related force field were carefully formulated and assembled following the procedure previously adopted for methane. The… (More)
DOI: 10.1021/jp3126158


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