Capture of carbon dioxide from air and flue gas in the alkylamine-appended metal-organic framework mmen-Mg2(dobpdc).

@article{Mcdonald2012CaptureOC,
  title={Capture of carbon dioxide from air and flue gas in the alkylamine-appended metal-organic framework mmen-Mg2(dobpdc).},
  author={T. M. Mcdonald and Woo Ram Lee and J. A. Mason and B. Wiers and C. Hong and J. Long},
  journal={Journal of the American Chemical Society},
  year={2012},
  volume={134 16},
  pages={
          7056-65
        }
}
Two new metal-organic frameworks, M(2)(dobpdc) (M = Zn (1), Mg (2); dobpdc(4-) = 4,4'-dioxido-3,3'-biphenyldicarboxylate), adopting an expanded MOF-74 structure type, were synthesized via solvothermal and microwave methods. Coordinatively unsaturated Mg(2+) cations lining the 18.4-Å-diameter channels of 2 were functionalized with N,N'-dimethylethylenediamine (mmen) to afford Mg(2)(dobpdc)(mmen)(1.6)(H(2)O)(0.4) (mmen-Mg(2)(dobpdc)). This compound displays an exceptional capacity for CO(2… Expand
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