Calixarene-Based Fluorescent Sensors for Cesium Cations Containing BODIPY Fluorophore.

  title={Calixarene-Based Fluorescent Sensors for Cesium Cations Containing BODIPY Fluorophore.},
  author={Alexis Depauw and Naresh Kumar and Minh-Huong Ha-Thi and Isabelle Leray},
  journal={The journal of physical chemistry. A},
  volume={119 23},
New fluorescent molecular sensors based on a calix[4]arene biscrown-6 ether as coordination site and BODIPY derivative as signaling unit were synthesized, and their photophysical properties were characterized. The complexation properties of these sensors with potassium and cesium cations were investigated using both steady-state and time-resolved fluorescence methods. The studies show that the sensitivity with cations depends upon the position of substituted coordination site on the BODIPY core… CONTINUE READING
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