COHERENT NUCLEAR MOTION IN A CONDENSED-PHASE ENVIRONMENT : WAVE-PACKET APPROACH AND PUMP-PROBE SPECTROSCOPY

@article{Muhlbacher1999COHERENTNM,
  title={COHERENT NUCLEAR MOTION IN A CONDENSED-PHASE ENVIRONMENT : WAVE-PACKET APPROACH AND PUMP-PROBE SPECTROSCOPY},
  author={Lothar Muhlbacher and Andreas Lucke and Reinhold Egger},
  journal={Journal of Chemical Physics},
  year={1999},
  volume={110},
  pages={5851-5860}
}
A quantum-mechanical Gaussian wave-packet approach to the theoretical description of nuclear motions in a condensed-phase environment is developed. General expressions for the time-dependent reduced density matrix are given for a harmonic potential surface, and the exact quantum dynamics is found for a microscopic system-plus-bath model. Particular attention is devoted to the influence of initial correlations between system and bath for the outcome of a pump–probe experiment. We show that the… 
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