CH(phenol)-Bridged Bis(imino)pyridines as Compartmental Supports for Diiron Precatalysts for Ethylene Polymerization: Exploring Cooperative Effects on Performance

@article{Chen2018CHphenolBridgedBA,
  title={CH(phenol)-Bridged Bis(imino)pyridines as Compartmental Supports for Diiron Precatalysts for Ethylene Polymerization: Exploring Cooperative Effects on Performance},
  author={Q. Chen and Wenjuan Zhang and G. A. Solan and Randi Zhang and Liwei Guo and Xiang Hao and Wen-Hua Sun},
  journal={Organometallics},
  year={2018},
  volume={37},
  pages={4002-4014}
}
A family of six CH(phenol)-bridged bimetallic bis(imino)pyridine-iron(II) chlorides, CH(C6H4-4-OH){2′-(4-C6H2-2,6-(R1)2N═CMe)-6′-(2″,6″-(R2)2-4-(R3)C6H2N═CMe)C5H3N}2Fe2Cl4 [R1 = R2 = Me, R3 = H, Fe1; R1 = R2 = Et, R3 = H, Fe2; R1 = Me, R2 = Et, R3 = H, Fe3; R1 = Me, R2 = i-Pr, R3 = H, Fe4; R1 = R2 = R3 = Me, Fe5; R1 = R2 = Et, R3 = Me, Fe6], has been synthesized by the reaction of the corresponding compartmental ligand with 2 equiv of FeCl2·4H2O. The molecular structure of Fe6 reveals an… Expand
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