• Chemistry
  • Published 1987

CALCULATION OF THERMODYNAMIC PROPERTIES OF REAL FLUIDS AND VAPOR-LIQUID EQUILIBRIA BY USING A CANONICAL PARTITION FUNCTION (I) THERMODYNAMIC PROPERTIES OF PURE FLUIDS

@inproceedings{Ai1987CALCULATIONOT,
  title={CALCULATION OF THERMODYNAMIC PROPERTIES OF REAL FLUIDS AND VAPOR-LIQUID EQUILIBRIA BY USING A CANONICAL PARTITION FUNCTION (I) THERMODYNAMIC PROPERTIES OF PURE FLUIDS},
  author={Shin'ichiro Ai},
  year={1987}
}
The Anderson-Prausnitz equation of state has been improved by modifying the attractive term of the generalized van der Waals canonical partition function. In this modification, the parameter characterizing the intermolecular attractive forces is considered to depend not only on temperature but also on density. By this new equation of state the calculated results for pressure and fugacity coefficient of pure gases have slightly better accuracy than those by the original Anderson-Prausnitz… CONTINUE READING