C-H···N hydrogen-bonding interaction in 7-azaindole:CHX3 (X=F, Cl) complexes.

@article{Shirhatti2014CHNHI,
  title={C-H···N hydrogen-bonding interaction in 7-azaindole:CHX3 (X=F, Cl) complexes.},
  author={Pranav R. Shirhatti and Dilip Kumar Maity and Surjendu Bhattacharyya and Sanjay Wategaonkar},
  journal={Chemphyschem : a European journal of chemical physics and physical chemistry},
  year={2014},
  volume={15 1},
  pages={109-17}
}
The C-H···Y (Y=hydrogen-bond acceptor) interactions are somewhat unconventional in the context of hydrogen-bonding interactions. Typical C-H stretching frequency shifts in the hydrogen-bond donor C-H group are not only small, that is, of the order of a few tens of cm(-1) , but also bidirectional, that is, they can be red or blue shifted depending on the hydrogen-bond acceptor. In this work we examine the C-H···N interaction in complexes of 7-azaindole with CHCl3 and CHF3 that are prepared in… CONTINUE READING
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