C-Alkylation of Phenyithio Aziridine Carboxylates

@inproceedings{SeebachDieter1987CAlkylationOP,
  title={C-Alkylation of Phenyithio Aziridine Carboxylates},
  author={SeebachDieter and HanerRobert},
  year={1987}
}
  • SeebachDieter, HanerRobert
  • Published 1987
  • Chemistry
  • The N-t-butyl and N-benzyl aziridine carboxylic acid phenylthiol esters are deprotonated in the α-carbonyl position and alkylated by alkyl halides, by aldehydes, and by nitrostyrene. The diastereoselectivities in the additions to trigonal centers range from 72 to 88% (rel. topicity lk with benzaldehyde). 

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