Bromopyrrole alkaloids isolated from the Patagonian bryozoan Aspidostoma giganteum.

@article{LauraPPatio2014BromopyrroleAI,
  title={Bromopyrrole alkaloids isolated from the Patagonian bryozoan Aspidostoma giganteum.},
  author={C LauraPPati{\~n}o and C. Muniain and M. E. Knott and L. Puricelli and J. Palermo},
  journal={Journal of natural products},
  year={2014},
  volume={77 5},
  pages={
          1170-8
        }
}
Nine new bromopyrrole alkaloids, aspidostomides A-H and aspidazide A (1-9), were isolated from the Patagonian bryozoan Aspidostoma giganteum. Aspidostomides A-H have dibromotyrosine- or bromotryptophan-derived moieties forming either linear amides or pyrroloketopiperazine-type lactams with a bromopyrrole carboxylic acid as a common structural motif. On the other hand, aspidazide A is a rare asymmetric acyl azide formed by an N-N link of two different pyrroloketopiperazine lactams and is the… Expand
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