Breathing 3 D Frameworks with T-Shaped Connecting Ligand Exhibiting Solvent Induction , Metal Ions Effect and Luminescent Properties

To study the structural effects in three-dimensional porous coordination polymers, three novel flexible porous coordination polymers—[Cd2(bpdc)2](DMF)3(H2O) (1) and [M(bpdc)](DMF)(H2O) (M = Cd (2), Zn (3))—have been synthesized under solvothermal conditions with d10 block metal ions and T-shaped connecting ligand. Complexes 1–3 crystallize in different… CONTINUE READING