Boranediyl‐ and Diborane(4)‐1,2‐diyl‐Bridged Platinum A‐Frame Complexes

  title={Boranediyl‐ and Diborane(4)‐1,2‐diyl‐Bridged Platinum A‐Frame Complexes},
  author={Carina Brunecker and Jonas H. Muessig and Merle Arrowsmith and F. Fantuzzi and A. Stoy and Julian Boehnke and A. Hofmann and R{\"u}diger Bertermann and B. Engels and H. Braunschweig},
  journal={Chemistry (Weinheim an Der Bergstrasse, Germany)},
  pages={8518 - 8523}
  • Carina Brunecker, Jonas H. Muessig, +7 authors H. Braunschweig
  • Published 2020
  • Chemistry, Medicine
  • Chemistry (Weinheim an Der Bergstrasse, Germany)
  • Abstract Diplatinum A‐frame complexes with a bridging (di)boron unit in the apex position were synthesized in a single step by the double oxidative addition of dihalo(di)borane precursors at a bis(diphosphine)‐bridged Pt0 2 complex. While structurally analogous to well‐known μ‐borylene complexes, in which delocalized dative three‐center‐two‐electron M‐B‐M bonding prevails, theoretical investigations into the nature of Pt−B bonding in these A‐frame complexes show them to be rare dimetalla(di… CONTINUE READING

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