Bis(μ2-iso­propyl­imido-κ2 N:N)bis­[(η5-cyclo­penta­dien­yl)(ethenolato-κO)titanium(IV)]


The title dinuclear half-sandwich complex, [CpTi(OCH=CH2)(μ2-N-iPr)]2 (Cp = cyclo-penta-dien-yl; iPr = isopropyl), was ob-tained from the reaction of Cp2TiCl2, n-butyl-lithium and iso-propyl-amine in tetra-hydro-furan. Each Ti(IV) atom is coordinated by one Cp ligand, one vin-yloxy unit and two bridging imido groups in a strongly distorted tetra-hedral… (More)
DOI: 10.1107/S1600536813033072


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@inproceedings{Haehnel2014Bis2isopropylimido2N, title={Bis(μ2-iso­propyl­imido-κ2 N:N)bis­[(η5-cyclo­penta­dien­yl)(ethenolato-κO)titanium(IV)]}, author={Martin Haehnel and Anke Spannenberg and Uwe Rosenthal}, booktitle={Acta crystallographica. Section E, Structure reports online}, year={2014} }