Bis(azido-κN)(di-2-pyridyl­amine-κ2 N 2,N 2′)palladium(II)

@inproceedings{Ha2012BisazidoNdi2pyridylamine2N2,
  title={Bis(azido-κN)(di-2-pyridyl­amine-κ2
N
2,N
2′)palladium(II)},
  author={Kwang Ha},
  booktitle={Acta crystallographica. Section E, Structure reports online},
  year={2012}
}
In the title complex, [Pd(N(3))(2)(C(10)H(9)N(3))], the Pd(II) ion is in a slightly distorted square-planar coordination environment. The ligator atoms comprise the two pyridine N atoms of the chelating di-2-pyridyl-amine (dpa) ligand and two N atoms from two azide anions. The dpa ligand coordinates the Pd atom in a boat conformation, the dihedral angle between the pyridine rings being 24.4 (1)°. The pyridine rings are somewhat inclined to the least-squares plane of the PdN(4) unit, making… CONTINUE READING

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