Biosynthesis of ambiguine indole alkaloids in cyanobacterium Fischerella ambigua.


Ambiguines belong to a family of hapalindole-type indole alkaloid natural products, with many of the members possessing up to eight consecutive carbon stereocenters in a fused pentacyclic 6-6-6-5-7 ring scaffold. Here, we report the identification of a 42 kbp ambiguine (amb) biosynthetic gene cluster that harbors 32 protein-coding genes in its native… (More)
DOI: 10.1021/cb400681n



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