Bioinorganic chemistry: Model offers intermediate insight.

Abstract

Reporting in Angewandte Chemie, Liu et al. describe a tractable and functional chemical model for a reaction intermediate that is central to a variety of biologically important processes. Their model, known as a ferric hydroperoxo–haem intermediate, is chemically analogous to intermediates that have been observed or proposed for several classes of enzymes… (More)
DOI: 10.1038/463168a

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