Bio-inspired polyene cyclization: aziridinyl polyene cyclization catalyzed by InBr(3).

Abstract

This communication describes a highly efficient aziridinyl polyolefin cyclization catalyzed by InBr(3) to synthesize chiral terpenoid bearing a 3-amino group in the A ring; both good yields and excellent asymmetric induction were achieved. 
DOI: 10.1039/b903696b

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