Benzoannelated Centropolyquinanes . Part 21 . I Centrohexaindane : Three Complementary Syntheses of the Highest Member of the Centropolyindane Family


The syntheses of centrohexaindane 1, a unique hydrocarbon bearing six mutually fused indane units in a centrohexacyclic, Td symmetrical, and topologically nonplanar framework is reported in full detail. Three independent and complementary synthetic routes have been developed making use of derivatives of the readily accessible centrotriindanes 9, 10 and 11… (More)

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