Behaviour of silver-silver oxalate and mercury-mercurous oxalate electrodes in formamide at different temperatures

@inproceedings{Dash1975BehaviourOS,
  title={Behaviour of silver-silver oxalate and mercury-mercurous oxalate electrodes in formamide at different temperatures},
  author={Un Dash and Bimbadhar Nayak},
  year={1975}
}
The e.m.f. values of the cells: Pt, H2|H2C2O4(m)|Ag2C2O4-Ag (A) Pt, H2|H2C2O4(m)|HgC2O4-Hg (B) Hg-Hg2C2O4|H2C2O4(m)|Ag2C2O4-Ag (C) have been measured in formamide at nine temperatures ranging from 5 to 45°C. Values of the standard potentials (E°m) of silver-silver oxalate and mercury-mercurous oxalate electrodes and values of the e.m.f. of cell (C) can be expressed as equations obtained by using the least squares method: (A) E°m = 0.44642-1.042x10-3(t-25)+4.150x10-6(t-25)2 (B) E°m = 0.39438-1… CONTINUE READING