Behavior of rate coefficients for ion-ion mutual neutralization, 300-550 K.

@article{Miller2012BehaviorOR,
  title={Behavior of rate coefficients for ion-ion mutual neutralization, 300-550 K.},
  author={Thomas M. Miller and Nicholas S Shuman and Albert A Viggiano},
  journal={The Journal of chemical physics},
  year={2012},
  volume={136 20},
  pages={204306}
}
Rate coefficients k(MN) have been measured for a number of anion neutralization reactions with Ar(+) and Kr(+) over the temperature range 300-550 K. For the first time, the data set includes anions of radicals and other short-lived species. In the present paper, we review these results and make note of correlations with reduced mass, electron binding energy of the anion (equivalent to the electron affinity of the corresponding neutral), and temperature, and compare with expectations from… CONTINUE READING

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